Differentiation of Strong Acids by Conductometric Titration in Glacial Acetic Acid
β Scribed by Dr. B. Sansoni
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 131 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
The kinetics of oxidation of some neutralized β£-hydroxy compounds such as glycolic (GA), lactic (LA), β£-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,
## Abstract Iron complexes (tpa)Fe(OTf)~2~ (1) and (bpmen)Fe(OTf)~2~ (2) [tpa=trisβ(2βpyridylmethyl)amine; bpmen=__N,Nβ²__βbisβ(2βpyridylmethyl)β__N,Nβ²β__dimethylβ1,2βethylenediamine] were found to catalyze the __in situ__ formation of AcOOH from H~2~O~2~ and AcOH in the course of olefin oxidations.
The kinetics of the reduction of hexachloroiridate(IV) by benzyl alcohol (PhCH 2 OH), some substituted benzyl alcohols (XC 6 H 4 CH 2 OH, where X = NO 2 , Cl and OMe), and benzhydrol (Ph 2 CHOH) to give benzaldehyde, the corresponding substituted benzaldehydes and benzophenone, respectively, were in