## Abstract The origin of the carbon skeleton of verrucarin E **(1)** from acetate as precursor is confirmed. Incorporation studies with [1,2β^13^C]βacetate have demonstrated that two acetoacetate units couple together as shown in pattern **A** __(Scheme 2)__ and not as in **B**. Analysis of the de
Differential hydrogen exchange during the biosynthesis of fatty acids in Anacystis nidulans: the incorporation of [2,2,2-2H3, 2-13Co;1] acetate
β Scribed by A. Gavin McInnes; John A. Walter; Jeffrey L.C. Wright
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 293 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
13C NMR studies (with simultaneous 'H, *H-decoupling) of 13C, 2H-labelled methyl palmitate showed a gradation of 'H-retention along the adyl chain. The results are rationalized within the known steps of fatty acid biosynthesis.
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