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Studies on the biosynthesis of terrecyclic acid A II confirmation of the cyclization mechanism and hydrogen shifts using [2-2H3]acetate and [213C2H3]acetate

✍ Scribed by Akira Hirota; Masahira Nakagawa; Heiichi Sakai; Akira Isogai; Kazuo Furihata; Haruo Seto

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 237 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89266-7

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✦ Synopsis

Feeding experiments with t2-3H Iacetate and [2-13C2H in Aspergillus terreus Thorn No.14 indicatsd that the hydrogen a

Table 1 Alpha-and beta-deuterium substituted shifts in 13 C-NMR spectra of III. (pprn\ 111 from feeding experiment with III from feeding experiment with Zarbon [2-3x31acetate I2-'3c2li31acetate CL I? (I z-1

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