Differential Calorimeter for Heats of Formation. of Solid Alloys. Heats of Formation of Alloys of the Noble Metals
β Scribed by Oriani, R. A.; Murphy, W. K.
- Book ID
- 121449836
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 657 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
## Heats of formation have been measured by liquid tin solution calorimetry for a complete series of Au-Cu alloys in equilibrium states at 720Β°K and for the same alloys at 320Β°K after rapid quenching from 873Β°K. The asymmetry in the heat of formation curve at 720Β°K is in accord with observations
The relative heats of formation for a series of solid-solution alloys in the gold-palladium system have been measured in a liquid-metal solution calorimeter. The thermodynamic quantity is found to be exothermio over the entire composition range with a maximum value at approximately 40 at. oh palladi