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Diethyl and methyl-tert-buthyl ethers as new solvents for aerogels preparation

✍ Scribed by Lermontov, Sergey A.; Malkova, Alena N.; Yurkova, Lyudmila L.; Straumal, Elena A.; Gubanova, Nadezhda N.; Baranchikov, Alexander Ye.; Ivanov, Vladimir K.


Book ID
121337555
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
755 KB
Volume
116
Category
Article
ISSN
0167-577X

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Preparation of new azobenzene crown ethe
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New azobenzene crown ether p-tert-butylcalix [4]arenes (6 and 7) have been synthesized by reductive coupling reactions between two nitrobenzene groups. Their isomerization and switchable binding properties towards Na + and K + were studied by 1 H NMR spectroscopy. The results showed that Na + prefer