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Diesel-like fuel obtained by pyrolysis of vegetable oils

✍ Scribed by Daniela G. Lima; Valerio C.D. Soares; Eric B. Ribeiro; Daniel A. Carvalho; Érika C.V. Cardoso; Flávia C. Rassi; Kleber C. Mundim; Joel C. Rubim; Paulo A.Z. Suarez


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
111 KB
Volume
71
Category
Article
ISSN
0165-2370

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✦ Synopsis


The pyrolysis reactions of soybean, palm tree, and castor oils were studied. The pyrolytic products were analyzed by CG-FID, CG-MS, and FTIR, showing the formation of olefins, paraffins, carboxylic acids, and aldehydes. The adequate choice of distillation temperature (DT) ranges made it possible to isolate fuels with physical-chemical properties comparable to those specified for petroleum based fuels. The catalytic upgrading of the soybean pyrolytic fuel over HZSM-5 zeolite at 400 • C was also studied and has shown a partial deoxygenation of the pyrolytic products.


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