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Diene Dissolution of the Heavier Alkaline Earth Metals

✍ Scribed by Olaf Michel; Hiroshi Kaneko; Hayato Tsurugi; Koji Yamamoto; Karl W. Törnroos; Reiner Anwander; Kazushi Mashima

Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
465 KB
Volume
2012
Category
Article
ISSN
1434-1948

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The reaction of lithium[bis(dimethylphosphanyl)(trimethyl-(SiMe 3 )] 3 } -(8) was obtained. This compound is not only the first reported hexacoordinated magnesate, but also the first silyl)methanide] Li[(PMe 2 ) 2 C(SiMe 3 )] with BeCl 2 gave the homoleptic compound Be[(PMe 2 ) 2 C(SiMe 3 )] 2 (5) w