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Diels–Alder reactions of methyl- N -acyl-α,β-dehydroalaninates with cyclopentadiene

✍ Scribed by Bueno, M. P.; Cativiela, C.; Finol, C.; Mayoral, J. A.; Jaime, C.

Book ID
124169240
Publisher
NRC Research Press
Year
1987
Tongue
French
Weight
314 KB
Volume
65
Category
Article
ISSN
0008-4042

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Asymmetric Diels–Alder and Inverse-Electron-Demand Hetero-Diels–Alder Reactions of β,γ-Unsaturated α-Ketoesters with Cyclopentadiene Catalyzed by N,N′-Dioxide Copper(II) Complex
✍ Yin Zhu; Xiaohong Chen; Mingsheng Xie; Shunxi Dong; Zhen Qiao; Dr. Lili Lin; Dr. 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 328 KB 👁 1 views

## Abstract Highly enantioselective Diels–Alder (DA) and inverse‐electron‐demand hetero‐Diels–Alder (HDA) reactions of β,γ‐unsaturated α‐ketoesters with cyclopentadiene catalyzed by chiral __N__,__N′__‐dioxide–Cu(OTf)~2~ (Tf=triflate) complexes have been developed. Quantitative conversion of β,γ‐un