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Diels–Alder reaction of β-chloro-α,β-unsaturated aldehydes with cyclopentadiene: an experimental and theoretical study

✍ Scribed by Barhoumi-Slimi, Thouraya M.; Essalah, K.; Sanhoury, M. A. K.; Ourévitch, M.; El Gaied, M. M.


Book ID
121733799
Publisher
Springer
Year
2013
Tongue
English
Weight
898 KB
Volume
25
Category
Article
ISSN
1040-0400

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## Abstract Highly enantioselective Diels–Alder (DA) and inverse‐electron‐demand hetero‐Diels–Alder (HDA) reactions of β,γ‐unsaturated α‐ketoesters with cyclopentadiene catalyzed by chiral __N__,__N′__‐dioxide–Cu(OTf)~2~ (Tf=triflate) complexes have been developed. Quantitative conversion of β,γ‐un