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Diels–Alder cycloaddition of acetylene gas to a polycyclic aromatic hydrocarbon bay region

✍ Scribed by Fort, Eric H.; Jeffreys, Matthew S.; Scott, Lawrence T.

Book ID
118228998
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
934 KB
Volume
48
Category
Article
ISSN
1359-7345

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Gas-phase Diels–Alder cycloaddition of benzyne to an aromatic hydrocarbon bay region: Groundwork for the selective solvent-free growth of armchair carbon nanotubes
✍ Eric H. Fort; Lawrence T. Scott 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 285 KB

Benzyne, generated in the gas phase by pyrolysis of phthalic anhydride, has been shown to undergo Diels-Alder cycloaddition to the bay region of perylene, a typical polycyclic aromatic hydrocarbon, under solvent-free conditions in a high temperature flow system. The initial cycloadduct spontaneously