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Diels−Alder Reactivity of Polycyclic Aromatic Hydrocarbon Bay Regions: Implications for Metal-Free Growth of Single-Chirality Carbon Nanotubes

✍ Scribed by Fort, Eric H.; Donovan, Patrick M.; Scott, Lawrence T.


Book ID
118232486
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
191 KB
Volume
131
Category
Article
ISSN
0002-7863

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Gas-phase Diels–Alder cycloaddition of b
✍ Eric H. Fort; Lawrence T. Scott 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 285 KB

Benzyne, generated in the gas phase by pyrolysis of phthalic anhydride, has been shown to undergo Diels-Alder cycloaddition to the bay region of perylene, a typical polycyclic aromatic hydrocarbon, under solvent-free conditions in a high temperature flow system. The initial cycloadduct spontaneously