Diels-alder reactions with ethyl 1-benzofuran-3-carboxylates
✍ Scribed by Kilâmetâev, A. S.; Shulâts, E. E.; Shakirov, M. M.; Rybalova, T. V.; Tolstikov, G. A.
- Book ID
- 120519463
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2013
- Tongue
- English
- Weight
- 452 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1070-4280
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1,3-Butadiene-2-carboxylates derived from certain chiral alcohols are good substrates for a highly efficient asymmetric Diels-Alder reaction, which permits the preparation of optically active heterocyclic, cyclohexane and hydrindane systems.
Diels-Alder cycloaddition reactions of I-aryl-4-dimethylamino-2-phenyl-1 ,?-diazabncadicrlrs with rnonophenyl and diphenylketenes, resulting in high yields of pyrirnidin-h-one derivatives are reported. Cycloaddition reaction of hetero-dienes have been shown to be of great potentia! for