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Diels-Alder Reactions of Push-Pull Olefins I. Reactions of Dicyanovinyl Acylates with Cyclopentadiene, 1,3-Cyclohexadiene, and Anthracene

✍ Scribed by Martin Dees, Hans-Hartwig Otto

Book ID
113013161
Publisher
Springer Vienna
Year
1998
Tongue
English
Weight
137 KB
Volume
129
Category
Article
ISSN
0026-9247

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PM3 calculations of the pull-push dienes in the Diels-Alder reactions with acetonitrile and acrylonitrile are presented. Two of the pull-push dienes, Idimethylamino-I -iodoisoprene and I -fluoro-I -dimethylaminoisoprene where studied. In the iodo isomer the C-Z bond can be easily broken and the actu