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ChemInform Abstract: PM3 Calculations of Diels-Alder Reactions of “Pull-Push” Activated Isoprenes with Aceto- and Acrylonitrile.

✍ Scribed by B. S. JURSIC; Z. ZDRAVKOVSKI

Book ID
112021102
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
26
Category
Article
ISSN
0931-7597

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PM3 calculations of Diels-Alder reaction
PM3 calculations of Diels-Alder reactions of “pull-push” activated isoprenes with aceto- and acrylonitrile
✍ Branko S. Jursic; Zoran Zdravkovski 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 656 KB

PM3 calculations of the pull-push dienes in the Diels-Alder reactions with acetonitrile and acrylonitrile are presented. Two of the pull-push dienes, Idimethylamino-I -iodoisoprene and I -fluoro-I -dimethylaminoisoprene where studied. In the iodo isomer the C-Z bond can be easily broken and the actu