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Diels-Alder reactions of a 6-arenyl fulvene with dienes and dienophiles and related chemistry

✍ Scribed by Vijay Nair; G. Anilkumar; K.V. Radhakrishnan; K.C. Sheela; Nigam P. Rath

Book ID
108378820
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
524 KB
Volume
53
Category
Article
ISSN
0040-4020

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A novel approach to periplanone-b involv
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✍ Serge G. Cauwberghs; Pierre J. De Clercq 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 289 KB

The 6-step sequence to trienone 2, a known intermediate for the total synthesis of periplanone-B, involves the conversion of 2 into 5 using dilithiated propadiene, the IMDA of 4 to E-adducts 1 and 6, the conversion of 2 to diol S via a radical anion promoted cleavage of the oxygen bridge, and a in-s