Diels-Alder Addition of Dicyclopentadiene with Cyclopentadiene in Polar Solvents
β Scribed by ZHANG, X; JIANG, Q; XIONG, Z; ZOU, J; WANG, L; MI, Z
- Book ID
- 123305896
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 510 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1005-9040
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π SIMILAR VOLUMES
Starting from (R)-(+)-and from (S)-(-)-camphor the chiral alcohols 1: 2 and 3 have been prepared; their acrylates II underwent TiCl,(OR),-promoted Diels-Alder additTons to cyclopentadiene giving efficiently in a predictable manner either the (2R)-or the (2S)-adducts III with up to virtually quantita
191 a) Dr. A. Meyer, Stuttgart is thanked for the elemental analyses; b) Gd5CIVC2 is monoclinic, space group P2,/c (No. 14), a=918.2(3), b=1612.0(5), C = 1288.6(4) pm,/3= 119.86(2)"; Z = 4 ; R=0.026 with 3539 reflexions I > 2 a (I).