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Dielectric studies of hydrogen bonded ternary systems: Acetonitrile + alcohols + benzene

✍ Scribed by K. Sarojini; T. Thenappan

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 229 KB
Volume: 151
Category: Article
ISSN: 0167-7322
DOI: 10.1016/j.molliq.2009.10.016

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✦ Synopsis

Any molecule which has a hydrogen atom attached directly to oxygen or nitrogen is capable of hydrogen bonding. The molecular complexes formed by hydrogen have particularly attracted considerable attention to understand the nature of the bond. The hydrogen bonded complexes formed by acetonitrile with certain alcohols such as tertiary butyl alcohol, isoamyl alcohol, cyclohexyl alcohol, hexyl alcohol and diethylene glycol in benzene were studied. The dipole moments of 1:1 complexes of the above said systems were determined at 308 K. The dipolar increments for these systems were computed from the bond angle data available from molecular orbital studies. All these studied systems show that polarization interaction dominates in all the complexes.

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Dielectric studies of hydrogen bonded ternary systems: Acetonitrile&#xa0;+&#xa0;alcohols&#xa0;+&#xa0;benzene

✦ Synopsis

Dielectric studies of hydrogen bonded ternary systems: Acetonitrile + alcohols + benzene