Dielectric properties of the hydrate and deuterate of CBrClF2
β Scribed by D. Yu. Stupin
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1980
- Tongue
- English
- Weight
- 339 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0022-4766
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PMR spectra of substituted 4-piperidones in base and salt forms in D,O, water and other solvents are reported, and spectral characteristics interpreted in terms of equilibria between free ketone and 4,4-dideuteroxy (or hydroxy) forms. It is shown that 1-mono and 1,3-disubstituted-4piperidones exist
The quadrupole coupling constant. K, for the deutercn in the DHO-molecule is found to be about 1(X, larger than Kin the D20-molecule in partly deuteratell pJtasaium oxalate monohydrxe. It increases slightly with the temperature, anr' this increase ia exp:ained qualitatively as being rke to the stret