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Isotope effect in the 2H - NMR-spectra of partly deuterated hydrates

✍ Scribed by B. Pedersen; K. Håland

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
344 KB
Volume
2
Category
Article
ISSN
0009-2614

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✦ Synopsis

The quadrupole coupling constant. K, for the deutercn in the DHO-molecule is found to be about 1(X, larger than Kin the D20-molecule in partly deuteratell pJtasaium oxalate monohydrxe. It increases slightly with the temperature, anr' this increase ia exp:ained qualitatively as being rke to the stretching of the hydrogen bond.

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