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Dielectric Constant of Carbon Tetrachloride and Tertio-Butanol Mixtures

✍ Scribed by R. van Loon; J. P. Dauchot; A. Bellemans

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 363 KB
Volume: 77
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19680770704

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✦ Synopsis

The static dielectric constant of CC14, (CH3)sCOH and their mixtures has been measured in the liquid region between 0 and 50°C. Applying the Onsager-Kirkwood-Frohlich theory and extrapolating to infinite dilution, we found I .74*0.04 debye for the permanent dipole moment of the (CH&COH molecule. At intermediate concentrations there is clear tendency to the formation of complexes of alcohol molecules with their dipoles antiparallel. At high concentrations complexes with a parallel dipolar alignment predominate.

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