Die vier isomeren 1.4-Dimethyl-cyclohexanole-(2)
✍ Scribed by Hückel, Walter ;Ibrahim, Mohamed Gamal El-Dine
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1958
- Tongue
- English
- Weight
- 524 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0009-2940
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The structures of four isomeric dicyano-dispiro [2.4.2.0] dec-5-enes have been determined by a combination of proton NMR. spectroscopy, chemical equilibration experiments and dipole moment measurements.
## Abstract It has been shown by different methods that of the two 1,1‐dimethyl‐cyclohexan‐3‐ol‐2‐carboxylic acids described in two previous papers the acid m.p. 161° represents the trans and the other one, m.p. 118°, the cis form. The approximate proportions of these compounds obtained by catalyti
Gcf. ,, 74,91 ,, 12,35% Das Produkt erstarrt nicht beim Abkiihlen bis -loo. Ein Phenylurethan dieses Die Analysen wurden in unscrer mikroanalytischen Abteilung von Hrn. TV. Maiaser Alkohols konnte nicht erhalten werden. ausgefiihrt. Organisch-chemisches Laborstorium der Eidg. Technischen Hochschule,