## Abstract Among the reactions available to synthetic chemists for the construction of new CC bonds, the Claisen rearrangement is one of the most powerful, elegant, and well‐characterized methods. A genuinely new variant, the Belluš–Claisen rearrangement came to light a quarter of a century ago:
✦ LIBER ✦
Die Belluš-Claisen-Umlagerung
✍ Scribed by Jozef Gonda
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 263 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Bei der thermischen Umlagerung von __cis__‐4‐(__p__‐Tolyloxy)‐2‐buten‐[1‐^14^C] bei Temperaturen von etwa 200° entsteht zu ca. 60% das normale Umlagerungsprodukt 3‐(2′‐Hydroxy‐5′‐methyl‐phenyl)‐1‐buten‐[4‐^14^C] und zu ca. 40% als Produkt der «anormalen Umlagerung» 3‐(2′‐Hydroxy‐5′‐meth