Dicyclohexylammonium 1-(2-hydroxy-1-naphthyl)-2-naphtholate
✍ Scribed by Yuan, Ji-Xin ;Shen, Zhen-Lu ;Li, Li ;Song, Xin-Yuan ;Jin, Zhi-Min
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 501 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 12 H 24 N + ÁC 20 H 13 O 2 À , the naphtholate anions are linked via an O-HÁ Á ÁO hydrogen bond, and are connected to the dicyclohexylammonium cations by N-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
The molecule of the title compound, C 12 H 10 O 2 , is planar, with an intramolecular O-HÁ Á ÁO hydrogen bond between the hydroxy group and the carbonyl O atom. The structure is stabilized by intermolecular C-HÁ Á Á and offsetstacking interactions.
The crystal structure of the title compound, C 23 H 22 O 2 , which exists in the enol form, is stabilized by an intramolecular hydrogen bond. The dihedral angle between the naphthyl ring system and the aromatic ring of the t-BuC 6 H 4 group is 23.50 (10) .