Dicopper(II) complexes with sulphur bridge: Syntheses, spectral and electrochemical properties
β Scribed by Uday Mukhopadhyay; Debashis Ray
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 565 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0253-4134
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π SIMILAR VOLUMES
Oxalato-bridged dicopper(II) complexes [{CuL(H 2 O)} 2 (Β΅-ox)]-(ClO 4 ) 2 (1-4), where L is a bidentate chelating heterocyclic base such as 2,2Π-bipyridine (bpy, 1), 1,10-phenanthroline (phen, 2), dipyridoquinoxaline (dpq, 3) and dipyridophenazine (dppz, 4), were prepared by treatment of copper(II)
Three new polynuclear Mn II complexes with chloroacetate bridges were obtained and characterized by X-ray diffraction: 2), and [Mn(Β΅-ClCH 2 COO) 2 (phen)] n (3). The Mnβ’β’β’Mn distance for 1 (3.624 A Λ) is smaller than for 2 (4.613 A Λ) and 3 (4.530 A Λ); this is in agreement with the number of carbox