ChemInform Abstract: Dicopper(II) Complexes with Sulfur Bridge: Syntheses, Spectral and Electrochemical Properties
β Scribed by Uday Mukhopadhyay; Debashis Ray
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Oxalato-bridged dicopper(II) complexes [{CuL(H 2 O)} 2 (Β΅-ox)]-(ClO 4 ) 2 (1-4), where L is a bidentate chelating heterocyclic base such as 2,2Π-bipyridine (bpy, 1), 1,10-phenanthroline (phen, 2), dipyridoquinoxaline (dpq, 3) and dipyridophenazine (dppz, 4), were prepared by treatment of copper(II)
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The compounds [Cu II 2 Co III 2 (H 2 dea) 2 (dea) 4 ]X 2 (Solv) n [X = Cl (1), Br (2), SCN (3), O 2 CMe (4), I ( 5); Solv = H 2 O or/and CH 3 OH, DMF, n = 1-4] were synthesised by the reaction of zero-valent copper with cobalt(II) salts in non-aqueous (CH 3 OH, DMF, DMSO) solutions of diethanolamine