In the title complex, [CoCl 2 (C 5 H 5 NO) 4 ], the Co atom is in an elongated octahedral environment, de®ned by two Cl À ions and four N atoms of 3-hydroxypyridine ligands. The Co atom lies on a special position with crystallographic twofold rotation symmetry. Individual molecules are linked by int
Dichlorotetrakis(3-hydroxypyridine-κN)nickel(II)
✍ Scribed by Zhang, Xian-Fa ;Gao, Shan ;Huo, Li-Hua ;Lu, Zhen-Zhong ;Zhao, Hui
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 295 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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In the title complex, [PdCl 2 (C 13 H 14 N 2 O 2 )], the central Pd II atom is bonded to two pyridine N atoms and two terminal Cl atoms. The coordination geometry of the Pd atom is square planar with a slight tetrahedral distortion. The two PdÐN distances are 2.029 (3) and 2.057 (3) A Ê , and the NÐ
The title compound, [CuCl 2 (C 10 H 8 N 2 )], has twofold symmetry and the coordination geometry around the Cu II atom is distorted square-planar. There are weak intermolecular CuÁ Á ÁCl interactions, forming a chain structure in the crystal.