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Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides

✍ Scribed by Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken

Book ID: 119957423
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 783 KB
Volume: 106
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00313a032

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Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling reaction of a secondary alkyl grignard reagent with organic halides

✍ Tamio Hayashi; Mitsuo Konishi; Makoto Kumada 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 260 KB

Swmnary: Dichloro[l,l~-bis(diphenylphosphino)ferrocene]palladium(II) was found to be an effective catalyst for the cross-coupling reaction of see-butylmagnesium chloride with bromobenzene, B-bromostyrene, and Z-bromopropene to give the corresponding see-butyl derivatives in exceedingly high yields.