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Dichlorido­[1-(2-methyl­benz­yl)-3-(2,4,6-trimethyl­benz­yl)imidazolidin-2-yl­idene]ruthenium(II)

✍ Scribed by Arslan, Hakan ;VanDerveer, Don ;Yaşar, Sedat ;Özdemir, İsmail ;Çetinkaya, Bekir

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
174 KB
Volume
63
Category
Article
ISSN
1600-5368

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Dichloro­[3-(1-naphthyl­meth­yl)-1-(2,4,6-trimethyl­benz­yl)imidazolidin-2-yl­idene]ruthenium
✍ Arslan, Hakan ;VanDerveer, Don ;Özdemir, İsmail ;Yaşar, Sedat ;Çetinkaya, Bekir 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 255 KB

In the title compound, [RuCl 2 (C 24 H 26 N 2 )], the multidentate ligand functions as both an arene and a carbene, and occupies four coordination sites. The two Cl atoms complete a distorted octahedron about the Ru atom.

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In the crystal structure of the title compound, C 17 H 15 ClN 4 S, the benzothiazole, imidazolidine and benzene rings are twisted relative to each other.

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The title compound, C 15 H 9 NO 3 , was synthesized from phthalic anhydride and 4-aminobenzaldehyde. The dihedral angle between the planes of the phthalimide moiety and the benzene ring is 56.22 (2) . organic papers o2294 Xin-Gang Liu et al. C 15 H 9 NO 3

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The crystal structure of the title compound, C 12 H 14 O 5 ÁH 2 O, displays a supramolecular structure via O-HÁ Á ÁO hydrogen bonds. Nostacking is observed.