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Dicarbenes. The Preparation and Some Reactions of 1,4-Bis[α-diazobenzyl]benzene 1

✍ Scribed by MURRAY, ROBERT W.; TROZZOLO, ANTHONY M.

Book ID
126102366
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
474 KB
Volume
26
Category
Article
ISSN
0022-3263

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Preparation and Some Reactions of 1H-1,4
Preparation and Some Reactions of 1H-1,4-Benzothiazine Ylides (= 1H-1,4-Benzothioniaazin-4-ide)
✍ George M. Iskander; Ibrahim E. Khawad; Ghariballa Yousif; Keith Fisher; C. Kay F 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 431 KB 👁 1 views

A series of fifteen IH-1,4-benzothiazine ylides were obtained by alkylation of the corresponding 4H-1,4-benrothiazines 1. Ylides of type 2 g ~ r showed slight [I, 21 rearrangements upon thermolysis besides main dealkylation to 1 and olefin production. The ylides of this type underwent redox reaction