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The Preparation and Some Reactions of α-t-Acetylenic Ethers 1

✍ Scribed by HENNION, G. F.; BOISSELLE, ARMAND P.


Book ID
121336278
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
568 KB
Volume
26
Category
Article
ISSN
0022-3263

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Chemistry of acetylenic ethers XXXVI. Pr
✍ H. J. Boonstra; L. Brandsma; Miss A. M. Wiegman; J. F. Arens 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 694 KB

## Abstract Aldehydes can be converted into 1‐alkylthio‐1‐alkenes II (thioenol ethers) __via__ either α‐chlorothioethers I by elimination of hydrogen chloride or, better, thioacetals VI by acid catalysed elimination of thiol. Bromination of the thioenol ethers II followed by subsequent dehydrobromi