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DIBISYLDIPHOSPHENE: NEW ROUTES AND FIRST ASPECTS OF ITS REACTIVITY

✍ Scribed by Ranaivonjatovo, Henri; Escudié, Jean; Couret, Claude; Satgé, Jacques

Book ID
127286484
Publisher
Informa UK (Taylor & Francis)
Year
1987
Weight
355 KB
Volume
31
Category
Article
ISSN
0308-664X

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Sodium dithionite, which is known to cause dehalogenation of a-halo carbonyl compounds, also induces dehalogenation of protected 2-iodo-2-deoxyglycosides. Combined with the well-known iodonium-mediated haloalkoxylation, this reaction provides an easy, mild and highly stereoselective route for prepar