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New Aspects of the Impact Reactivity of Nitramines

✍ Scribed by Svatopluk Zeman


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
277 KB
Volume
25
Category
Article
ISSN
0721-3115

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Desilylation of Ξ±-trimethylsilyl nitrami
✍ C.Peter Lillya; Thomas P. Sassi πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 144 KB

Fluoride-induced desilylation of a trimethylsilylcyclopropyl nitramine generated the first known nitramine a-anion, which was trapped in situ by electrophiles (H20, D20, and CH3CHO). In contrast, a trimethylsilylmethyl nitramine gave a product resulting from elimination of the elements of trimethyls