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Diastereotopic exchange in the square-planar platinum(II) complex, (N,N'-dimethylethylenediamine)bis(guanosine)platinum(II)

✍ Scribed by Cramer, Roger E.; Dahlstrom, Phillip L.

Book ID
127008506
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
633 KB
Volume
24
Category
Article
ISSN
0020-1669

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## Abstract The mechanism of substitution water exchange reactions in square planar trans‐Pt[(NH~3~)~2~T(H~2~O)]^n+^ complexes is studied (Tο£ΎH~2~O, NH~3~, OH^βˆ’^, F^βˆ’^, Cl^βˆ’^, Br^βˆ’^, H~2~S, CH~3~S^βˆ’^, SCN^βˆ’^, CN^βˆ’^, PH~3~, CO, CH~3~^βˆ’^, H^βˆ’^, C~2~H~4~). The trans effect is explained in terms of σ‐do