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A Density Functional Study of S N 2 Substitution at Square-Planar Platinum(II) Complexes

✍ Scribed by Cooper, Jason; Ziegler, Tom

Book ID
124074320
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
125 KB
Volume
41
Category
Article
ISSN
0020-1669

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The trans effect in square-planar platin
The trans effect in square-planar platinum(II) complexesβ€”A density functional study
✍ Zdenek Chval; Miroslav Sip; Jaroslav V. Burda πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 319 KB πŸ‘ 1 views

## Abstract The mechanism of substitution water exchange reactions in square planar trans‐Pt[(NH~3~)~2~T(H~2~O)]^n+^ complexes is studied (Tο£ΎH~2~O, NH~3~, OH^βˆ’^, F^βˆ’^, Cl^βˆ’^, Br^βˆ’^, H~2~S, CH~3~S^βˆ’^, SCN^βˆ’^, CN^βˆ’^, PH~3~, CO, CH~3~^βˆ’^, H^βˆ’^, C~2~H~4~). The trans effect is explained in terms of σ‐do