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Solvent effects in square planar complexes: Kinetics of substitution at [1-(2-hydroxyphenyl)-3,5-diphenylformazanato]palladium(II) complexes

✍ Scribed by Sijbe Balt; Jan Meuldijk; Arie A. Wismeijer

Publisher: Springer
Year: 1981
Tongue: English
Weight: 511 KB
Volume: 6
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00620744

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## Abstract The reaction of LiN(SiMe~3~)~2~ with two equivalents of 2‐, 3‐, or 4‐cyanopyridine followed by the addition of half an equivalent of [PdCl~2~(PhCN)~2~] gives neutral 1,3,5‐triazapentadienato complexes of the general formula [Pd{HNC(Py)NC(Py)NH}~2~] (Py = 2‐pyridyl 1, 3‐pyridyl 2, 4‐pyri