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Diastereoselective Synthesis of α-Oxyamines via Gold-, Silver- and Copper-Catalyzed, Three-Component Couplings of α-Oxyaldehydes, Alkynes, and Amines in Water.

✍ Scribed by Baosheng Huang; Xiaoquan Yao; Chao-Jun Li

Book ID
101995937
Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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Diastereoselective Synthesis of α-Oxyami
Diastereoselective Synthesis of α-Oxyamines via Gold-, Silver- and Copper-Catalyzed, Three-Component Couplings of α-Oxyaldehydes, Alkynes, and Amines in Water
✍ Baosheng Huang; Xiaoquan Yao; Chao-Jun Li 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 106 KB

## Abstract The three‐component couplings of α‐oxyaldehydes, alkynes, and amines in water were investigated by using gold, silver and copper catalysts. Gold(I) was found to be the most effective catalyst in this reaction to afford propargylamines in good yields and moderate diastereoselectivities.