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Diastereoselective synthesis of glycosylated prolines as α-glucosidase inhibitors and organocatalyst in asymmetric aldol reaction

✍ Scribed by Jyoti Pandey; Namrata Dwivedi; Nimisha Singh; A.K. Srivastava; A. Tamarkar; R.P. Tripathi

Book ID
108074236
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
154 KB
Volume
17
Category
Article
ISSN
0960-894X

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Diastereoselective Synthesis of Glycosyl
Diastereoselective Synthesis of Glycosylated Prolines as α-Glucosidase Inhibitors and Organocatalyst in Asymmetric Aldol Reaction.
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C-Glycosidic phosphonates were synthesized by the addition of pyranosidic and furanosidic glycosyl radicals to ot-phosphonoacrylates which occurred with high diastereoselectivity towards the formation of n-C-glycosidic phosphonates. The products are useful substrates for the synthesis of complex hig