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Diastereoselective Synthesis of Glycosylated Prolines as α-Glucosidase Inhibitors and Organocatalyst in Asymmetric Aldol Reaction.

✍ Scribed by Jyoti Pandey; Namrata Dwivedi; Nimisha Singh; A. K. Srivastava; A. Tamarkar; R. P. Tripathi


Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Diastereoselective free-radical synthesi
✍ Hans-Dieter Junker; Nga Phung; Wolf-Dieter Fessner 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 266 KB

C-Glycosidic phosphonates were synthesized by the addition of pyranosidic and furanosidic glycosyl radicals to ot-phosphonoacrylates which occurred with high diastereoselectivity towards the formation of n-C-glycosidic phosphonates. The products are useful substrates for the synthesis of complex hig