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Diastereoselective synthesis of (E)-1-trimethylsilyl-3-en-1-ynes by palladium-catalyzed cross-coupling reaction between trimethylsilylethynylzinc chloride and stereoisomeric mixtures of 1-bromo-1-alkenes

โœ Scribed by Bianca Patrizia Andreini; Adriano Carpita; Renzo Rossi

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
132 KB
Volume
27
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Swnmary: In the stereospecific pallad&m-cata2yzed cross-coupling reaction of trimethytsilylethynylzinc chloride, (El-I-bromo-I-a2kenes react preferentially in the presence of the cowespending (Z)-stereoisomers.

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