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Diastereoselective Synthesis of Cyclododeca-1,6-diallenes ( = cyclododeca-l,2,6,7-tetraenes)

✍ Scribed by Christoph Boss; Reinhart Keese


Publisher
John Wiley and Sons
Year
1997
Tongue
German
Weight
418 KB
Volume
80
Category
Article
ISSN
0018-019X

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✦ Synopsis


The reaction of 3b with H-as the nucleophile using Sml,/Pdo remained unsuccessful [21] [22].


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Synthesis of [14C6-3,4,7,8,11,12]-(1E,5E
✍ Bruce N. Diel; Mingcheng Han; Jonathan M. White πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 French βš– 87 KB πŸ‘ 1 views

## Abstract Trimerization of butadiene in the presence of Ni(0) affords (1__E__,5__E__,9__E__)‐cyclododeca‐1,5,9‐triene **1** (__ttt__‐CDT), (1__E__,5__E__,9__Z__)‐cyclododeca‐1,5,9‐triene **2** (__ttc__‐CDT), and other isomers/oligomers. After optimization of reaction conditions, [^14^C~6~‐3,4,7,8