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ChemInform Abstract: Diastereoselective Synthesis of Cyclododeca-1,6-diallenes (= Cyclododeca-1,2,6,7-tetraenes).

✍ Scribed by C. BOSS; R. KEESE

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Trimerization of butadiene in the presence of Ni(0) affords (1__E__,5__E__,9__E__)‐cyclododeca‐1,5,9‐triene **1** (__ttt__‐CDT), (1__E__,5__E__,9__Z__)‐cyclododeca‐1,5,9‐triene **2** (__ttc__‐CDT), and other isomers/oligomers. After optimization of reaction conditions, [^14^C~6~‐3,4,7,8