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Diastereoselective synthesis of 3-amino-1,2-diols by reductive alkylation of 2,3-dialkoxynitriles

✍ Scribed by Pierre Hutin; Marc Larchevêque

Book ID
108379661
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
126 KB
Volume
41
Category
Article
ISSN
0040-4039

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✍ Pei Qiang Huang; Si Li Wang; Hong Zheng; Xiang Su Fei 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 117 KB

The first asymmetric synthesis of (2R, 3R)-3-amino-l-benzyl-2-methylpyrrolidine, the parent diamine of antipsychotic agent, emonapride, from (S)-malic acid was achieved via a highly diastereroselective reductive alkylation.