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Diastereoselective SmI2 mediated cascade radical cyclisations of methylenecyclopropane derivatives — syntheses of paeonilactone B and 6-epi-paeonilactone A

✍ Scribed by Boffey, Raymond J.; Whittingham, William G.; Kilburn, Jeremy D.

Book ID: 120380989
Publisher: Royal Society of Chemistry
Year: 2001
Weight: 255 KB
Volume: 5
Category: Article
ISSN: 1472-7781
DOI: 10.1039/b009513n

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📜 SIMILAR VOLUMES

ChemInform Abstract: Diastereoselective

ChemInform Abstract: Diastereoselective SmI2-Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives — Syntheses of Paeonilactone B and 6-epi-Paeonilactone A.

✍ Raymond J. Boffey; William G. Whittingham; Jeremy D. Kilburn 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

ChemInform Abstract: Diastereoselective

ChemInform Abstract: Diastereoselective SmI2-Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives — A Synthesis of Paeonilactone B.

✍ R. J. BOFFEY; M. SANTAGOSTINO; W. G. WHITTINGHAM; J. D. KILBURN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 2 views

Diastereoselective SmI 2 -Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives -A Synthesis of Paeonilactone B. -Using the title cascade reaction from (VII) to (IX) as key step the natural product paeonilactone B (XIV) is synthesized in an efficient manner. The relative stereoc