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ChemInform Abstract: Diastereoselective SmI2-Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives — Syntheses of Paeonilactone B and 6-epi-Paeonilactone A.

✍ Scribed by Raymond J. Boffey; William G. Whittingham; Jeremy D. Kilburn

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
ChemInform Abstract: Diastereoselective SmI2-Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives — A Synthesis of Paeonilactone B.
✍ R. J. BOFFEY; M. SANTAGOSTINO; W. G. WHITTINGHAM; J. D. KILBURN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

Diastereoselective SmI 2 -Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives -A Synthesis of Paeonilactone B. -Using the title cascade reaction from (VII) to (IX) as key step the natural product paeonilactone B (XIV) is synthesized in an efficient manner. The relative stereoc