𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Diastereoselective reduction of β-hydroxyketones with amineboranes in the presence of lithium perchlorate

✍ Scribed by Chatla Narayana; M.Rama Reddy; Max Hair; George W Kabalka


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
161 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


The reduction of 13-hydroxyketones with amineboranes in the presence of lithium perchlorate produces the corresponding anti 1,3-diols as major products.


📜 SIMILAR VOLUMES


Allylation of Quinones with Allylsilane
✍ Prof. Dr. Junes Ipaktschi; Dipl.-Chem. Akbar Heydari 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 333 KB 👁 1 views

Experinzen fal Procedure 2 : Complex 1 [2] (0.70 g) was dissolved in 60% HCIO, solution (30 mL). Within a few days red-brown hexagonal crystals of 2 precipitated (yield: 0.52 g, 3: Solid NaOH (1.0 g) was added to an aqueous solution (30 mL) of 6 [5a] (0.80 5). and the color of the solution changed f

Reduction of perchlorate at the dropping
✍ F. Bet-Pera; B. Jaselskis 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 452 KB

Abstractdtalytic reduction of perchlorate in tha presence of molybdenum(V1) in 1 M acid solution depends not only on the concentration of perchlorate but also on the nature and the concentration of other anions present. The anionic species effect is attributed to the competitive ion pair formation w