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Diastereoselective Multicomponent Cyclizations of Fischer Carbene Complexes, Lithium Enolates, and Allylmagnesium Bromide Leading to Highly Substituted Five- and Six-Membered Carbocycles

✍ Scribed by José Barluenga; Iván Pérez-Sánchez; Marcos G. Suero; Eduardo Rubio; Josefa Flórez

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 218 KB
Volume: 12
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200600491

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## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke