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Diastereoselective Intramolecular Friedel–Crafts Cyclizations of Substituted Methyl 2-(1H-indole-1-carbonyl)acrylates: Efficient Access to Functionalized 1H-Pyrrolo[1,2-a]indoles

✍ Scribed by Patil, Dadasaheb V.; Cavitt, Marchello A.; France, Stefan

Book ID: 111886608
Publisher: American Chemical Society
Year: 2011
Tongue: English
Weight: 928 KB
Volume: 13
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol202431x

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ChemInform Abstract: Diastereoselective

ChemInform Abstract: Diastereoselective Intramolecular Friedel—Crafts Cyclizations of Substituted Methyl 2-(1H-Indole-1-carbonyl)acrylates: Efficient Access to Functionalized 1H-Pyrrolo[1,2-a]indoles.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Efficient synthesis of functionalized 3H

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Synthesis of 9,9-Disubstituted 9H-Pyrrol

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✍ Kazuhiro Kobayashi; Kenichi Hashimoto; Hiroo Hashimoto; Hideaki Kondo; Hisatoshi 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 152 KB

## Abstract A novel method is reported for the synthesis of 9,9‐disubstituted 9__H__‐pyrrolo[1,2‐__a__]indoles. Cyclization of 1‐[2‐(1‐aryl(or methyl)ethenyl)phenyl]‐1__H__‐pyrroles, which can be easily prepared from 2‐(1‐aryl(or methyl)ethenyl)anilines, proceeds smoothly, in general, at 0° in the

ChemInform Abstract: Synthesis of 9,9-Di

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✍ Kazuhiro Kobayashi; Kenichi Hashimoto; Hiroo Hashimoto; Hideaki Kondo; Hisatoshi 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

## Abstract The novel method is performed in the presence of either a catalytic or stoichiometric amount of HI.