Diastereoselective epoxidation of allylic alcohols by t-butyl hydroperoxide/zeolites system
β Scribed by Laura Palombi; Francesco Bonadies; Arrigo Scettri
- Book ID
- 108378699
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 331 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0040-4020
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The epoxidation of chloromethylbutenes by t-butyl hydroperoxide in the presence of has been investigated. The inΓuence of important Mo(CO) 6 parameters on hydroperoxide conversion, selectivity of transformation to epoxy compound in relation to hydroperoxide used, yield in relation to oleΓn introduce
## Ε½ . The catalytic abilities of commercial K10-montmorillonite and molecular sieves 4 A and 13 X vs. oxidation of alcohols by t-butyl hydroperoxide were investigated. The K10-montmorillonite-catalyzed oxidation of secondary benzylic alcohols was found to proceed in good yield and selectivity wit