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Diastereoselective Diels–Alder Reaction of 5-(Indol-2-yl)-pyran-2-one

✍ Scribed by Daniele Passarella; Giordano Lesma; Marisa Martinelli; Alessandra Silvani; Margalida Cantò; Josè Hidalgo

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
89 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

AbstractÐ5-(Indol-2-yl)-pyran-2-one undergoes cycloaddition to electron-poor and electron-rich dienophiles. Lanthanide shift reagents have been shown to be ef®cient catalysts for the inverse electron demand Diels±Alder reactions. The bicycloadducts were formed with complete stereoselectivity. Aminolysis of bicycloadducts with primary amines is described.

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