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Diastereoselective and Enantiospecific Synthesis of γ-Substituted α,β-Unsaturated Nitriles from O - Protected Allylic Cyanohydrins

✍ Scribed by Baeza, Alejandro; Casas, Jesús; Nájera, Carmen; Sansano, José M.

Book ID
125931346
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
252 KB
Volume
71
Category
Article
ISSN
0022-3263

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Diastereoselective and Enantiospecific S
Diastereoselective and Enantiospecific Synthesis of γ-Substituted α,β-Unsaturated Nitriles from O-Protected Allylic Cyanohydrins.
✍ Alejandro Baeza; Jesus Casas; Carmen Najera; Jose M. Sansano 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 65 KB 👁 1 views

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Synthesis of γ-Hydroxy-α,β-unsaturated E
Synthesis of γ-Hydroxy-α,β-unsaturated Esters and Nitriles from Chiral Cyanohydrins
✍ Jan Marcus; Pauline J. van Meurs; Adrianus M.C.H. van den Nieuwendijk; Mathieu P 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 145 KB

The Horner-Wittig reaction of cyanomethyl-and carbethoxymethyl diphenylphosphine oxides with a range of O-protected chiral a-hydroxy aldehydes is described. The a-hydroxy aldehydes were prepared with high enantiomeric purity from chiral O-protected cyanohydrins. The g-hydroxy-a,b-unsaturated compoun